Do the original devices contain PC-compatible serial ports, or something like the SCC which might (note that I've not checked this) be more flexible on account of their support for SDLC etc.? Or are they bit-banging it, or perverting SPI hardware?
I can't speak for TComPort and the rest, but I've just checked serial.pp (to which I was the most recent contributor) and there's no immediately-obvious way to do it, and I suspect that you'll be getting very heavily OS-dependent.
On reception, I think you'll need to look for a parity error on each symbol: which could get messed up by buffering.
On transmission, I think you'll need to set the top bit explicitly to mark or space: which might not work properly if symbols are already queued for transmission.
MarkMLl