It's too sad that there is no synapse for 64 bit Lazarus. 
Synapse works just fine on Lazarus 64 bit.
Have you test it with Intel or ARM ? RasPi 4 is a ARM system. As i know this is a new Target, not often used yet
Linux on Intel 32 and 64 bit and ARM 32 bit.
Unfortunately I don't have a spare RPI4 at the moment and they are hard to come by.
(And I just repurposed my last RPI3)
But like you said yourself, a freezing Lazarus shouldn't be because of Synapse.
So there must be something else wrong.
(And TS said Indy was installed just before so my guess is that's the culprit

)