I don't know what you are talking about...
The "Align" property of many components? Hmmm, can't be, because there is no setting for "center in window".
The "Align" in the context menu? Could be because now there is a "center in window" in the "horizontal" and "vertical" boxes. I tested it - it seems to work. BUT: This is valid only for the size of the form at designtime. When you later resize the form at runtime (or even at designtime) the button will stick to its old position. And this is the same as in Delphi. So, I'd say this is rather useless...
The best way to center a control inside its container is using the anchor editor:
https://wiki.freepascal.org/Anchor_Sides#Via_the_Anchor_Editor. Select the button that you want to center, open the anchor editor (menu "View"). First go to the "Left anchoring" box, select the form in the combobox, and click the center button below the combobox - this centers the button horizontally. You can resize the form, and the button will follow. Repeat with the "Top anchoring" settings, and the button is also centered vertically. (BUT: now you cannot drag the button with the mouse any more since the requirement for centering and mouse interaction are mutually excluding).