If you mean the path to save your app preferences then use GetAppConfigDir.
It works correctly in FPC trunk.
If you mean paths returned by Java Environment class methods (
https://developer.android.com/reference/android/os/Environment.html) then AFAIK it is not yet accessible either through FPC RTL or through LAMW. For LAMW it would need another component which would encapsulate the Environment class.
Another option is to use hard coded paths, usable of course only for your private project. On my device:
primary card: /storage/sdcard0/
external card: /storage/extSdCard/