I get the same problem ("Error on connect: connection refused") even if I put a slash behind the URL.
Lazarus 0.9.28.2, FPC 2.2.4, lNET SVN, Windows 7
Installed Synapse and with one line of code could fetch a web page, no problem. Of course it is blocking, etc. so it would be nice if lNet can be fixed. The demo, httpclienttest.lpi also dies with "Error creating SSL CTX: SSLCTXNew". If I delete the SSL component it runs, but with connection refused error on any URL.
Firewall is turned off but I expect it has to do with Windows 7.