This can't be all you are doing. Because having only one series with a single point would make the chart draw the point in its center and adjust the axis scale depending on the value of the point, very unlikely that the axis limits will be 0 and 100 in both directions. See the left chart in the attached project, it is created on the sole information that you are giving.
The second chart has a modification of the Range parameters of both axes. TChartAxis.Range holds two values, Min and Max, as well as to booleans, UseMin and UseMax, in order to activate these limits and to override the automatic axis scaling. After selecting them to 0 and 100, respectively, the axis limits are set exactly like that. But note that this works only as long as the series values are within this range, i.e. when a series value is > 100 or < 0 then automatic scaling comes in again and determines the corresponding axis limit. This was made to make sure that all data points are visible.
If you, by all means, want the axis limits to be 0 and 100, no matter what the series values are, you can set Chart.Extent.XMin, .XMax, .YMin, .YMax, .UseXMin, .UseXMax, .UseYMin, .UseYMax as you need.