Well the "while i = 0" will run forever.
Your code is the same as the following (with extra begin end for more clarity)
program project1;
var
i: integer;
b: boolean;
begin
i := 0;
b := true;
if b = true then
BEGIN
while i = 0 do
{empty statement};
END
else
BEGIN
while i = 1 do
begin // this code might be quite long
i := (i + 1) mod 2
end;
END;
end.
Since "b=true" the first loop, with the "empty statement" is executed. And since "i=0" and i never changes, that loop runs forever.
If you are in the debugger, you can use pause to interrupt => however, (OS dependent), pause may create a temporary thread, in which case you must open the thread window and switch to your main thread.