You can either share the code and so get eyes here to debug it for you, or debug it yourself.
Compile with debugging information, open a Call Stack window (and perhaps Watches, Local Variables etc. as you need) and single step in the debugger, starting from your main form's OnCreate or OnShow handler (or some other event that suits your case), until you reach the statement(s) that give rise to the access violation. Once you have pinpointed where the problem lies, you'll probably be able to figure out what needs amending to cure it. If not, come back here.