The best and most up-to-date documentation is the source code itself.
Add gvector to the uses clause of your or a dummy project. CTRL+leftclick on "gvector", and Lazarus will open the unit in the source editor. There are not too many methods of TVector. Most of them are clear by just reading their name. Some of them were not clear to me: What is "Front" and "Back"? Select "Front" in the interface section, press CTRL+SHIFT+ArrowDown to go to the implementation, and from there I learned that the funtion Front returns just the first vector element. Similarly with Back - it is the last vector element.
Once you are used to this kind of navigation through the sources you will need documentation only in a few cases.