As indicated in the documentation (see "README.txt", Chapter "6. GENERAL NOTES"), you can't use the standard (i.e. Delphi or FPC) "Classes.pas" unit.
At least, not without some modifications.
One of the samples provided, "GetWebPage" (
https://github.com/FChrisF/LLCL-samples/tree/master/FPC/GetWebPage), is an illustration of how to modify the LLCL, in order to use the standard "Classes.pas" unit in your own code.
A small utility program, "LClassesMake", is provided with this sample. Compile it, then run the executable (it's a console program) in your sub-directory containing all the LLCL units.
Practically, after the modifications done by "LClassesMake" the LLCL "Classes.pas" file is renamed in "LClasses.pas", and all of the other LLCL units are then using it (i.e. LClasses), instead of the standard one (Classes).